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Sulfur, 16S
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Sulfur
PronunciationTemplate:Infobox element/pronunciation
Alternative nameSulphur (pre-1992 British spelling)
AllotropesTemplate:Infobox element/symbol-to-allotropes
AppearanceLemon yellow sintered microcrystals
Mass numberTemplate:Infobox element/symbol-to-most-stable-isotope
Sulfur in the periodic table
Template:Infobox element/periodic table
Atomic number (Z)16
GroupTemplate:Infobox element/symbol-to-group
PeriodTemplate:Infobox element/symbol-to-period
BlockTemplate:Infobox element/block format
Electron configurationTemplate:Infobox element/symbol-to-electron-configuration
Electrons per shell2, 8, 6
Physical properties
Phase at STPTemplate:Infobox element/symbol-to-phase
Melting pointalpha (α-S8): 388.36 K ​(115.21 °C, ​239.38 °F)
Boiling point717.8 K ​(444.6 °C, ​832.3 °F)
Density (near r.t.)alpha (α-S8): 2.07 g/cm3
beta (β-S8): 1.96 g/cm3
gamma (γ-S8): 1.92 g/cm3
when liquid (at m.p.)1.819 g/cm3
Critical point1314 K, 20.7 MPa
Heat of fusionbeta (β-S8): 1.727 kJ/mol
Heat of vaporizationbeta (β-S8): 45 kJ/mol
Molar heat capacity22.75 J/(mol·K)
Vapor pressureTemplate:Infobox element/vapor pressure table
Atomic properties
Oxidation statesTemplate:Element-symbol-to-oxidation-state-data
ElectronegativityPauling scale: 2.58
Ionization energies
  • 1st: 999.6 kJ/mol
  • 2nd: 2252 kJ/mol
  • 3rd: 3357 kJ/mol
  • (more)
Covalent radius105±3 pm
Van der Waals radius180 pm
Template:Infobox element/spectral lines
Other properties
Natural occurrenceTemplate:Infobox element/symbol-to-occurrence
Crystal structurealpha (α-S8): ​Template:Infobox element/crystal structure (oF128)
Lattice constantsa = 1.0460 nm
b = 1.2861 nm
c = 2.4481 nm (at 20 °C)[1]
Crystal structurebeta (β-S8): ​Template:Infobox element/crystal structure (mP48)
Lattice constantsa = 1.0923 nm
b = 1.0851 nm
c = 1.0787 nm
β = 95.905° (at 20 °C)[1]
Thermal conductivity0.205 W/(m⋅K) (amorphous)
Electrical resistivity2×1015  Ω⋅m (at 20 °C) (amorphous)
Magnetic orderingdiamagnetic[2]
Molar magnetic susceptibilityalpha (α-S8): −15.5×10−6 cm3/mol (298 K)[3]
Bulk modulus7.7 GPa
Mohs hardness2.0
CAS Number7704-34-9
History
Namingfrom the Latin sulpur
Discoverybefore 2000 BCE[4]
SymbolTemplate:Infobox element/symbol-to-symbol-etymology
Recognized as an element byAntoine Lavoisier (1777)
Isotopes of sulfur
Template:infobox sulfur isotopes does not exist
Category Category: Sulfur
| references

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child table, as reused in {IB-S} Template:V
Main isotopes of Template:Infobox element/symbol-to-name
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References

  1. 1.0 1.1 Arblaster, John W. (2018). Selected Values of the Crystallographic Properties of Elements. Materials Park, Ohio: ASM International. ISBN 978-1-62708-155-9.
  2. Lide, D. R., ed. (2005). "Magnetic susceptibility of the elements and inorganic compounds". CRC Handbook of Chemistry and Physics (PDF) (86th ed.). Boca Raton (FL): CRC Press. ISBN 0-8493-0486-5.
  3. Weast, Robert (1984). CRC, Handbook of Chemistry and Physics. Boca Raton, Florida: Chemical Rubber Company Publishing. pp. E110. ISBN 0-8493-0464-4.
  4. "Sulfur History". Georgiagulfsulfur.com. Retrieved 2022-02-12.

One of these is a named reference. It may be cited in the containing article as

  • <ref name="magnet" /> for the source edited by Lide.
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